|
KMID : 1059519930370100888
|
|
Journal of the Korean Chemical Society
1993 Volume.37 No. 10 p.888 ~ p.894
|
|
|
Electrochemical Behaviors of Copper-1-(2-pyridylazo)-2-naphthol Complex in Acetonitrile
|
|
Bae Zun-Ung
Oh Sang-Oh
Song Hee-Bong
Park Tae-Myung
|
|
|
Abstract
|
|
|
|
The electrochemical behaviors of copper-1-(2-pyridylazo)-2-naphthol(Cu-PAN) complex in acetonitrile (AN) solution have been investigated by the use of cyclic voltammetry, DC-polarography, controlled potential coulometry and UV-Vis spectroscopy. Cu-PAN complex in acetonitrile exhibit three reduction waves at -1.27 V, -1.64 V and -2.08 V vs. Ag/AgNO3(AN). The numbers of electron involved in each reduction step was calculated with controlled potential coulometry, and reduction product was identified with UV-Vis spectrum. As the result, we proposed the reduction mechanism of the Cu-PAN complex in acetonitrile.
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|